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Metalloporphyrins contain Mn or Fe metals coordinated by four donor nitrogens in a square planar arrangement and have been reported to scavenge superoxide radicals (O 2 ) (Pasternack and Skowronek 1979), hydrogen peroxide (H 2 O 2 ), peroxynitrite (ONOO ) and hydroperoxides (LOOH) (Day et al

As a reducing agent, it is the main cellular antioxidant agent in the reduction of hydrogen peroxide (H 2 O 2 ) and lipid hydroperoxides (LOOH) catalyzed by glutathione peroxidases (GPXs)

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Importantly, the transport of GSH by MRP1 can be greatly stimulated by modulators such as verapamil 8

doi: 10.1002/(SICI)1097-4547(19980201)51:3 3.0.CO;2-B 27 LeeM