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In cell culture models of human macrophage foam cells, the inability to clear cholesterol from macrophages with compromised lysosome function continues even in the presence of compounds that stimulate efflux (161,163)

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For example, sulfur functionalization in the second shell alter the electronic structure of the FeN 4 site, increasing the electron density at the Fermi level and enhancing electron transfer from the active site to the key intermediate HO 2 , thereby boosting oxidase-like activity 126

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