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It is suggested that glutathione acts to remove any heme that has been inadvertently released into the cytoplasm, and that in normal circumstances there will be extremely low levels of heme in the cytoplasm, intracellular transfer of heme being conducted by vesicles and/or direct contact between intracellular membranes

10.1016/j.biopha.2020.110589 8

Gandhi et al., 2007

Tumour sensitization via the extended intratumoural release of a STING agonist and camptothecin from a self-assembled hydrogel

The heavy GCLC is both the catalytic unit and the regulatory site of GSH feedback inhibition, while the light subunit regulates the activity of the holo-enzyme by modulating the affinity of the two regulatory sites of GCLC, that for glutamate and that for glutathione thereby making the enzyme more efficient and less sensitive to feedback inhibition